A New Structure–Magnetism Relationship for Face‐Sharing Transition‐Metal Complexes with d3–d3 Electronic Configuration

Andrea Niemann; Ursula Bossek; Karl Wieghardt; Christian Butzlaff; Alfred X. Trautwein; Bernhard Nuber

doi:10.1002/anie.199203111

A New Structure–Magnetism Relationship for Face‐Sharing Transition‐Metal Complexes with d³–d³ Electronic Configuration

Andrea Niemann, Ursula Bossek, Karl Wieghardt^*, Christian Butzlaff, Alfred X. Trautwein, Bernhard Nuber

^*Korrespondierende/r Autor/-in für diese Arbeit

Institut für Physik

46 Zitate (Scopus)

Abstract

A through‐space interaction and not superexchange of the bridging ligands explains the antiferromagnetic coupling in dinuclear face‐sharing octahedral complexes with d³‐d³ electronic configuration. The metal‐metal distance is the only relevant structural parameter for the spin‐exchange coupling constants of a series of V 2II, Cr 2III, and Mn 2IV complexes.

Originalsprache	Englisch
Zeitschrift	Angewandte Chemie International Edition in English
Jahrgang	31
Ausgabenummer	3
Seiten (von - bis)	311-313
Seitenumfang	3
ISSN	0570-0833
DOIs	https://doi.org/10.1002/anie.199203111
Publikationsstatus	Veröffentlicht - 01.03.1992

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10.1002/anie.199203111

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abstract = "A through‐space interaction and not superexchange of the bridging ligands explains the antiferromagnetic coupling in dinuclear face‐sharing octahedral complexes with d3‐d3 electronic configuration. The metal‐metal distance is the only relevant structural parameter for the spin‐exchange coupling constants of a series of V 2II, Cr 2III, and Mn 2IV complexes.",

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A New Structure–Magnetism Relationship for Face‐Sharing Transition‐Metal Complexes with d³–d³ Electronic Configuration. / Niemann, Andrea; Bossek, Ursula; Wieghardt, Karl et al.
in: Angewandte Chemie International Edition in English, Jahrgang 31, Nr. 3, 01.03.1992, S. 311-313.

Publikation: Beiträge in Fachzeitschriften › Zeitschriftenaufsätze › Forschung › Begutachtung

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T1 - A New Structure–Magnetism Relationship for Face‐Sharing Transition‐Metal Complexes with d3–d3 Electronic Configuration

AU - Niemann, Andrea

AU - Bossek, Ursula

AU - Wieghardt, Karl

AU - Butzlaff, Christian

AU - Trautwein, Alfred X.

AU - Nuber, Bernhard

PY - 1992/3/1

Y1 - 1992/3/1

N2 - A through‐space interaction and not superexchange of the bridging ligands explains the antiferromagnetic coupling in dinuclear face‐sharing octahedral complexes with d3‐d3 electronic configuration. The metal‐metal distance is the only relevant structural parameter for the spin‐exchange coupling constants of a series of V 2II, Cr 2III, and Mn 2IV complexes.

AB - A through‐space interaction and not superexchange of the bridging ligands explains the antiferromagnetic coupling in dinuclear face‐sharing octahedral complexes with d3‐d3 electronic configuration. The metal‐metal distance is the only relevant structural parameter for the spin‐exchange coupling constants of a series of V 2II, Cr 2III, and Mn 2IV complexes.

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M3 - Journal articles

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JO - Angewandte Chemie International Edition in English

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