TY - JOUR
T1 - (1,4,7-Tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane)iron(III): A Model for the Iron-Sulfur Center in Nitrile Hydratase from Breribacterium, sp
AU - Beissel, Thomas
AU - Bürger, Kai Silke
AU - Voigt, Gottfried
AU - Wieghardt, Karl
AU - Butzlaff, Christian
AU - Trautwein, Alfred X.
PY - 1993/1/1
Y1 - 1993/1/1
N2 - Stable six-coordinate iron(III) complexes of the pendant arm macrocycles 1,4,7-tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane and 1,4,7-tris(mercaptopropyl)-1,4,7-triazacyclononane each of which provide a fac-N3S3 donor set have been synthesized and characterized by UV-vis and ESR spectroscopy. These complexes serve as a structural model for the bacterial enzyme nitrile hydratase from Brevibacterium, sp.
AB - Stable six-coordinate iron(III) complexes of the pendant arm macrocycles 1,4,7-tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane and 1,4,7-tris(mercaptopropyl)-1,4,7-triazacyclononane each of which provide a fac-N3S3 donor set have been synthesized and characterized by UV-vis and ESR spectroscopy. These complexes serve as a structural model for the bacterial enzyme nitrile hydratase from Brevibacterium, sp.
UR - http://www.scopus.com/inward/record.url?scp=0001551739&partnerID=8YFLogxK
U2 - 10.1021/ic00054a002
DO - 10.1021/ic00054a002
M3 - Journal articles
AN - SCOPUS:0001551739
SN - 0020-1669
VL - 32
SP - 124
EP - 126
JO - Inorganic Chemistry
JF - Inorganic Chemistry
IS - 2
ER -